Product ID:CHLORINATION TREATMENT, SATR
MSDS Date:02/01/1993
FSC:6850
NIIN:00N043189
MSDS Number: BRRFD

WORTHEN INDUSTRIES

3 EAST SPIT BROOK RD
NASHUA, NH 03060
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 603-888-5443

Preparer: DR. ROBERT BRAGOLE

Cage: 0G7C8

WORTHEN INDUSTRIES

NASHUA, NH 03060 US

Telephone: 603-888-5443

Cage: 0G7C8

ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (SARA III)

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: 97.81%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

S-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3,5-TRICHLORO-;

CAS: 87-90-1

RTECS: XZ1925000

Fraction By Weight: 2.19%

OSHA PEL N/K

ACGIH TLV: N/K

CONTACT OCCURS, USE PROTECTIVE CLOTHING IMPERVIOUS

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) 10,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:500-1000PPM, MINIMAL
ANESTH/NARCTC EFTS. OVER 1000PPM, MAY CAUSE DIZZ, DRUNKENESS. OVER
10,000PPM, CAN CAUSE CARD ARRHY, UNCON & DEATH. EYES:MAY CAUSE
PAIN, SLIGHT TRANSIENT (TEMPORARY) IRRIT W/ SLIGHT TRANSIENT
CORNEAL INJURY. VAP MAY IRRIT. SKIN: RPTD/PRLNG EXPOS MAY CAUSE
IRRIT, FLAKING/DRYING. (EFTS OF OVEREXP
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:SINGLE PRLNG EXPOS NOT LIKELY TO RSLT
IN ABSORPTION OF HARMFUL AMTS. INGEST:SINGLE DOSE ORAL TOX LOW. IF
ASPIR (LIQ ENTERS LUNG), MAY BE RAPIDLY ABSORBED THRU LUNGS & RSLT
IN INJURY TO OTHER BODY SYS. CHRONIC:BASED ON AVAIL DATA, RPTD
EXPOS NOT ANTIC TO CAUSE ANY ADVERSE EFTS. IN-VITRO MUTAGENIC TETS
NEGATIVE.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:EYES:IRRIGATE IMMED W/H2O FOR @ LEAST 15 MIN. SKIN:WASH OFF
IN FLOWING H2O. INGEST:DO NOT INDUCE VOMIT. CALL MD &/ OR TRANSPORT
TO EMER FACILITY IMMED. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG,
GIVE MO UTH-TO-MOUTH RESUSCITATION. IF BRTHG DFCLT, GIVE O2. CALL
MD. NOTE TO MD:BECAUSE RAPID ABSORPTION MAY OCCUR THRU LUNGS IF
ASPIR & CAUSE SYSTEMIC EFTS, DECISION OF WHETHER TO INDUCE VOMIT OR
(SUPDAT

Lower Limits:2.2%
Upper Limits:11.0%
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . ANY CLASS B EXTINGUISHING MEDIA CAN BE USED.
THOROUGHLY CLEAN EQUIPMENT AFTER USE.
Unusual Fire/Explosion Hazard:THERE IS A POSSIBILITY OF PRESSURE
BUILD-UP IN CLOSED CONTAINERS WHEN HEATED UP. USE WATER SPRAY TO
COOL CONTAINERS EXPOSED TO HEAT.

Spill Release Procedures:SMALL LEAKS:MOP UP, WIPE UP OR SOAK UP
IMMEDIATELY. REMOVE TO OUT-OF-DOORS. LARGE SPILLS:EVACUATE AREA.
CONTAIN LIQUID; TRANSFER TO CLOSED METAL CONTAINERS. KEEP OUT OF
WATER SUPPLIES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:HANDLE W/REASONABLE CARE. AVOID BRTHG
VAPS. STORE IN COOL DRY PLACE. CONC VAPS OF PROD ARE HVR/AIR & WILL
COLLECT IN LOW AREAS SUCH AS PITS, (SUPDAT)
Other Precautions:ALUMINUM IS NOT AN ACCEPTABLE MATERIAL OF
CONSTRUCTION FOR PUMPS, MIXERS, FITTINGS, STORAGE TANKS FOR
CHLORINATED PRODUCTS OR FORMULATIONS. METALLIC ALUMINUM & ZINC
POWDERS SHOULD BE AVOIDED.

Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW
THE EXPOSURE GUIDELINES. IN CONFINED OR POORLY VENTILATED AREAS,
USE AN NIOSH/ MSHA APPROVED POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS.
Ventilation:CONTROL AIRBORNE CONC BELOW EXPOS GUIDELINE. USE ONLY
W/ADEQ VENT. LOC EXHST VENT MAY BE NEC FOR SOME (SUPDAT)
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:SFTY EYE BATHS & SHOWERS SHLD BE NEARBY. FOR
BRIEF CNTCT, NO PREC OTHER THAN CLEAN BODY-COVERING CLTHG SHOULD
(SUPDAT)
Work Hygienic Practices:HANDLE ALL CHEMICALS WITH CAUTION & CARE.
Supplemental Safety and Health
FIRST AID PROC:NOT SHLD BE MADE BY ATTENDING MD. HNDLG/STOR
PREC:DEGREASERS, STOR TANKS, & OTHER CONFINED AREAS. DO NOT ENTER
AREAS WHERE VAPS SUSPECTED UNLESS SPEC BRTHG APPARATUS USED W/
OBSERVER PR ESENT. VENT:OPERATIONS. LETAL CONC MAY EXIST IN AREAS
W/POOR VENT. OTHER PROT EQUIP:BE NEEDED. WHEN RPTD/PRLNG (ING 3)

Boiling Pt:B.P. Text:168F,76C
Vapor Density:HVR/AIR
Spec Gravity:0.8 (H2O=1)
Evaporation Rate & Reference:FASTER/N-BUTYL ACETATE
Solubility in Water:DISPERSIBLE
Appearance and Odor:CLEAR LIQUID WITH A STRONG ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH ALUMINUM OR ZINC. REACTION WITH THESE METALS WILL
GENERATE CORROSIVE GAS.
Stability Condition to Avoid:AVOID OPEN FLAMES, WELDING ARCS OR OTHER
HIGH TEMPERATURE SOURCES WHICH INDUCE THERMAL DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE AND VERY SMALL
AMOUNTS OF PHOSGENE AND CHLORINE.

Waste Disposal Methods:WHEN DISP OF UNUSED CONTENTS, PREF OPTIONS ARE
TO SEND TO LICENSED RECLAIMER OR TO PERMITTED INCINERATORS. ANY
DISP PRACTICE MUST BE IN COMPLIANCE WITH FED, STATE & LOCAL
REGULATIONS. DO NOT DUMP INTO SEWERS, ON THE GROUND, OR INTO ANY
BODY OF WATER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.